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CZ8N62E21The finest beechwood cask

Our finest level of bourbon rests inside our largest oak barrels. As a result, not only do we emphasize the same distillation and quality process of our other bourbon, we also allow the product to rest longer in our barrels. With approximately 15 years in age, our highly sought after whisky is as smooth as can be. At just $109.99

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We take your privacy seriously. We will NEVER sell your data to anyone. It’s stored in a secure database and your personal information is never released or sold to any parties outside of The Barrel Shop. Period.Water exchange kinetics of isolated ferricytochrome C. Investigation by molecular dynamics simulations.
Molecular dynamics simulations were performed on a system of one iron-protoporphyrin IX complex in a simulation box containing 312 water molecules. The temporal evolution of the axial Fe coordination number, the magnitude of the Fe-Protoporphyrin IX axis-to-axis distance, and the hydrogen-bond properties of water molecules were monitored in an attempt to characterize the water exchange kinetics of ferricytochrome c as a function of temperature. The general characteristics observed at 250 K by this study were qualitatively similar to those reported in previous experimental and simulation studies of low-temperature water exchange kinetics. The water exchange rate was found to be controlled by a factor of seven from 100 K to 150 K, with an activation enthalpy of the order of 20 kcal mol(-1). A similar temperature dependence was observed in the fraction of water molecules in the hydrogen-bond network. The water exchange was found to occur via a pathway of two jumps, one from the gas phase to the first coordination shell, and a second

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